Friday 29 February 2008

No impact from Energy Saving Day

The UK's first Energy Saving Day has ended with no noticeable reduction in the country's electricity usage.

E-Day asked people to switch off electrical devices they did not need over a period of 24 hours, with the National Grid monitoring consumption.

It found that electricity usage was almost exactly what would have been expected without E-Day.

Colder weather than forecast in some regions may have led to higher use of heating, masking any small savings.

The event also received very little publicity, despite having backing from campaign groups such as Greenpeace, Christian Aid and the RSPB, and from major energy companies such as EDF, E.On and Scottish Power.
"I am afraid that E-Day did not achieve the scale of public awareness or participation needed to have a measurable effect," said E-Day's organiser Dr Matt Prescott in a message on his website.

The Grid's final figures showed national electricity consumption for the 24 hours (from 1800 Wednesday to 1800 Thursday) was 0.1% above the "business-as-usual" projection.

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Tuesday 26 February 2008

Nanoparticles could make hydrogen cheaper than gasoline

The hydrogen economy is getting a shot in the arm from a start-up that says its nanoparticle coatings could make hydrogen easy to produce at home from distilled water, and ultimately bring the cost of hydrogen fuel cells in line with that of fossil fuels.
QuantumSphere Inc. says it has perfected the manufacture of highly reactive catalytic nanoparticle coatings that could up the efficiency of electrolysis, the technique that generates hydrogen from water. Moreover, the coatings could also eliminate the need for expensive metals like platinum in hydrogen fuel cells.

Boasting 1,000 times the surface area of traditional materials, the coatings can be used to retrofit existing electrolysers to increase their efficiency to 85 percent--exceeding the Department of Energy's goal for 2010 by 10 percent. The scheme holds the promise of 96 percent efficiency by the time cars powered by hydrogen fuel cells hit automobile showrooms, according to the Santa Ana, Calif., company.

"Instead of switching 170,000 gas stations over to hydrogen, using our electrodes could enable consumers to make their own hydrogen, either in the garage or right on the vehicle," said Kevin Maloney, president, chief executive officer and co-founder of QuantumSphere. "Our nanoparticle-coated electrodes make electrolysers efficient enough to provide hydrogen on demand from a tank of distilled water in your car."

The first commercial product inspired by QuantumSphere's technology will debut later this year: a battery using a cathode coated with the startup's nanoparticles, thereby increasing its energy density 5x over alkaline cells and boosting power by 320 percent. The first commercial nonrechargeable batteries with this increased capacity will be announced by an as-yet-unnamed major U.S. battery maker in the second half of 2008.

QuantumSphere also claims to be able to improve rechargeable nickel-metal-hydride batteries to the point where they perform better than the less environmentally friendly lithium-ion batteries popular today.

QuantumSphere's plan is first to retrofit existing electrolysis equipment with its nanoparticle electrodes to boost efficiency. Next, it intends to partner with original equipment manufacturers to design at-home and on-vehicle electrolysers for making hydrogen from water for fuel cells. Finally, the company wants to work with fuel cell makers to replace their expensive platinum electrodes with inexpensive stainless-steel electrodes coated with nickel-iron nanoparticles.


by R.C.JOHNSON
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Friday 22 February 2008

Solar cell speeds hydrogen production

A solar cell that mimics photosynthesis has been used to make hydrogen directly from water. The prototype is inefficient, but the researchers who built it believe they can boost its efficiency, perhaps leading to a viable source of hydrogen to fuel cars and other vehicles.

The device, built by Thomas Mallouk of Pennsylvania State University and colleagues, works much like a solar cell called a Grätzel cell, using sunlight to knock electrons off dye molecules. But instead of being used to create a current, as in the Grätzel cell, the electrons are shuttled away from the dye and into a catalyst, where they split water molecules into oxygen and hydrogen ions in a reaction similar to one stage of natural photosynthesis.

Other dye-based approaches to splitting water haven't worked very well because the electrons often recombine with the dye before they can be used. Mallouk says that the problem was a matter of arranging the molecular circuitry to channel the electrons effectively, avoiding such “short circuits”.

His solution is to attach ruthenium-based dye molecules to a catalyst particle, clinging so closely that any electrons knocked out of the dye are directed into the catalyst. "The key thing is to get everything small and individually packaged," Mallouk told New Scientist.

In the new device, water is split a thousand times faster than in other dye-based cells.

Elegant and original
“The attractive feature of the work is that the dye is wrapped around the iridium oxide nanoparticles. This is a very elegant and original approach,” says Michael Grätzel of the Federal Institute of Technology in Lausanne, Switzerland, inventor of the Grätzel cell.

The approach may also be more promising than semiconductor approaches, which are incredibly complex, says James Durrant of Imperial College, London, UK.

Mallouk admits that so far the cell is very inefficient, as only around 1% of the light energy falling on it goes into splitting water, but he says that with some optimisation of the geometry and the molecules the efficiency could rise to 10% per cent. “Because we understand the relationship between intermolecular distances and electron transfer rates, we can in principle improve our system by changing the linking groups between molecules.”

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Biofuels 'need strict standards'

Biofuels should only be produced if they meet strict environmental standards, an international group of lawmakers have concluded.

The legislators said the fuels also had to deliver significant savings of greenhouse gas emissions.

If such criteria were met, they said there should be an urgent review of the tariffs that currently block imports into markets such as the EU and US.

The forum was hosted by Brazil, one of the world's biggest biofuel producers.

Biofuels have become a highly controversial issue, with claims that the rapid expansion of energy crops could threaten global food security, and add further pressure to sensitive ecosystems including rainforests.

It is also argued that in some cases the benefits to the climate of burning plant material instead of fossil fuels are outweighed by the energy needed to produce and transport biofuels, and by the release of carbon from soils by changes in land use.

The supporters of Brazilian ethanol argue, however, that huge areas of degraded cattle pasture are available to grow the crop, and that expansion of biofuel production does not require significant conversion of native ecosystems.

The meeting also failed to agree a framework for a new global agreement on measures to tackle climate change beyond 2012, with the Chinese delegation apparently reluctant to pre-empt the position of its government in forthcoming negotiations.

Lord Jay, the former head of the British Foreign Office, who had led the efforts to agree the framework, said there had been consensus over his claim that a massive increase was needed in the funds available to poorer countries to cope with the impacts of climate change.
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