Thursday 6 March 2008

Recycling carbon dioxide into petrol

A new reactor could make chemically recycling carbon dioxide back into petrol a worthwhile endeavour, US scientists say.

Researchers at Sandia National Laboratories, New Mexico, are to test a prototype device this spring, which will use concentrated solar energy to drive chemical reactions that split carbon dioxide molecules to get carbon monoxide. The same system was originally designed to split water to form hydrogen; and these two products can then be combined to synthesise liquid hydrocarbon fuels - such as methanol or petrol.

Splitting the stable carbon dioxide molecule is so tough that many researchers think the most economic course of action is simply to bury the greenhouse gas underground. And solar plants usually generate electricity, rather than split CO2.

But the Sandia team led by Jim Miller, Nathan Siegel and Richard Diver, who work on the 'Sunshine to Petrol' (S2P) project, think their device's chemical reactions are efficient enough to make it a worthwhile way of producing liquid fuels from CO2 . Ellen Stechel, manager of Sandia's fuel and energy transitions department, explained to Chemistry World that the ultimate aim is to have a series of solar-powered reactors, each collecting around 22kg of carbon dioxide and 18kg of water daily, and churning out some 2.5 gallons of petrol, based on target conversion efficiencies. 'Liquid fuels can be stored in trucks or piped using existing infrastructure,' Stechel pointed out.

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