The Waste Electrical and Electronic Equipment (WEEE) Directive requires 4kg of "e-waste" to be recycled per person.
Manufacturers have to fund recycling schemes, while retailers must offer take-back services to customers.
The legislation was supposed to be operational by August 2005 but was delayed by "major difficulties".
"E-waste", which includes PCs, games consoles, microwaves and washing machines, is the fastest-growing form of rubbish in the European Union.
The UK produces an estimated 1.2m tonnes of e-waste each year, most of which has been ending up in landfill sites.
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