Ozone could be a much more important driver of climate change than scientists had previously predicted, according to a study in Nature journal.
The authors say the effects of this greenhouse gas - known by the formula O3 - have been largely overlooked.
Ozone near the ground damages plants, reducing their ability to mop up carbon dioxide (CO2) from the atmosphere.
As a consequence, more CO2 will build up in the atmosphere instead of being taken up by plants.
This in turn will speed up climate change, say the Nature authors.
"Ozone could be twice as important as we previously thought as a driver of climate change," co-author Peter Cox, from the University of Exeter, UK, told the BBC News website.
Scientists already knew that ozone higher up in the atmosphere acted as a "direct" greenhouse gas, trapping infrared heat energy that would otherwise escape into space.
Ozone closer to the ground is formed in a reaction between sunlight and other greenhouse gases such as nitrogen oxides, methane and carbon monoxide.
Greenhouse emissions stemming from human activities have led to elevated ozone levels across large tracts of the Earth's surface.
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